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* Mary J. Blige, Beyonce. Alicia Keys, Black Eyed Peas, Andre 3000 and Usher joined a host of pop and rock acts at Radio City Music Hall Wednesday night for the official all-star, musical kick off to New York’s Fashion Week.

Comedian Denis Leary hosted the event, which was sponsored by Conde Nast Media Group and will air as a Fox special on September 26. 

Mary J. Bleezy took the stage decked in all-white – including a fedora. She belted covers of Elton John's "Sorry Seems to Be the Hardest Word" and Janis Joplin's "Piece of My Heart,"

Meanwhile, Keys’ set included a show-stopping rendition of “Heartburn,” from her latest CD “Diary of Alicia Keys.” 

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